Strictly diastereocontrolled photocyclodimerization of 2-anthracenecarboxylates tethered to cyclic tetrasaccharides.
نویسندگان
چکیده
Photocyclodimerization of 2-anthracenecarboxylate tethered to a cyclic nigerosylnigerose scaffold gave a single chiral cyclodimer (out of two achiral and two chiral stereoisomers) in 99% optical and 96% chemical yields, achieving the ultimate stereocontrol of the supramolecular photochirogenesis in aqueous solution at 25 °C.
منابع مشابه
Backbone-modified amphiphilic cyclic di- and tetrasaccharides.
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عنوان ژورنال:
- Chemical communications
دوره 48 73 شماره
صفحات -
تاریخ انتشار 2012